What kind of router do you have? Is it running the default firmware, or something more advanced like Tomato or DD-WRT?
Both Tomato and DD-WRT have options for blocking any site with a certain keyword or a certain word in the URL, so you could for example disable all sites with "proxy" in the URL. Do keep in mind that this might inhibit legitimate usage sometimes, if someone is trying to learn about network infrastructure for example, or is innocently reading an article about one of the
many other uses of the word. What environment are you using this in? Home? Workplace? School?